The new thioantimonate(V) (C3H10N)[NiSbS4(C6H18N4)]
Identifieur interne : 001763 ( Main/Exploration ); précédent : 001762; suivant : 001764The new thioantimonate(V) (C3H10N)[NiSbS4(C6H18N4)]
Auteurs : Ralph St Hler [Allemagne] ; Wolfgang Bensch [Allemagne]Source :
- Acta Crystallographica Section C [ 0108-2701 ] ; 2002-11.
Abstract
Turquoise crystals of the title salt, propylammonium di‐μ‐thio‐1:2κ4S‐dithio‐2κ2S‐tris(2‐aminoethyl)amine‐1κ4N‐antimony(V)nickel(II), (C3H10N)[NiSbS4(C6H18N4)] or [PAH][Ni(tren)SbS4] [where tren is tris(2‐aminoethyl)amine and PA is propylamine], were synthesized under solvothermal conditions by reacting [Ni(tren)2]Cl2, Sb and S in a solution of PA. The NiII ion is octahedrally surrounded by four N atoms of the tetradentate tren molecule and by two S atoms of the tetrahedral [SbVS4]3− anion, thus forming the anionic [Ni(tren)SbS4]− part of the compound. Charge balance is achieved through the PAH+ cation. An extended intermolecular hydrogen‐bonding network is observed between the anion and the cation.
Url:
DOI: 10.1107/S0108270102017754
Affiliations:
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